Recently, I had to migrate my VMNIC bindings from my Distributed Switches to my Standard Switches. Since my vCenter instance was being restored from backup (Failed 7.0 Update), I had to revert back to the ESXCLI.
Step 1: Validate Current vDS Switch Settings
esxcli network vSwitch dvs vmware list
Step 2: Remove NIC from vDS
esxcfg-vswitch -Q vmnic_Name -V PortID_of_dvSwitch dvSwitch_Name
Step 3: Verify VMNIC was removed from vDS
esxcli network vSwitch dvs vmware list
Step 4: Add VMNIC to vSS Switch (Can also be done by GUI but that is no fun)
esxcli network vSwitch standard uplink add --uplink-name=vmnic_Name --vswitch-name=vSS_Switch_Name